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102);">、技術(shù)介紹</span></strong></span></p><p style="margin: 5px 0px; text-indent: 32px; line-height: 2em;"><span style="font-size: 20px; font-family: 宋體, SimSun;"><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">在石油煉制、煤氣化、焦化、化工、制藥等行業(yè)原料處理和加工生產(chǎn)過(guò)程中，會(huì )產(chǎn)生不同濃度的含氨廢水。含氨廢水中的氨可以通過(guò)</span><span style="font-size: 19px; font-family: "Times New Roman", serif; color: black;">“</span><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">蒸氨工藝</span><span style="font-size: 19px; font-family: "Times New Roman", serif; color: black;">”</span><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">或</span><span style="font-size: 19px; font-family: "Times New Roman", serif; color: black;">“</span><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">氨吹脫</span><span style="font-size: 19px; font-family: "Times New Roman", serif; color: black;">”</span><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">工藝的方式得到氨氣，氨氣經(jīng)過(guò)反應器直接與硫酸反應制取硫酸銨產(chǎn)品。該方式無(wú)須外加熱源或蒸汽，不需要蒸發(fā)結晶。</span></span></p><p style="margin: 5px 0px; text-indent: 32px; line-height: 2em;"><span style="color: black; font-size: 20px; font-family: 宋體, SimSun;">蒸氨工藝制硫酸銨：含氨廢水與蒸氨塔高溫釜液換熱、升溫后進(jìn)入蒸氨塔，蒸氨塔再沸器用蒸汽進(jìn)行間接加熱，將廢水中的氨以氨氣的形式從塔頂采出，經(jīng)過(guò)反應器直接與硫酸反應制取硫酸銨產(chǎn)品。</span></p><p style="margin: 5px 0px; text-indent: 32px; line-height: 2em;"><span style="font-size: 20px; font-family: 宋體, SimSun;"><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">氨吹脫工藝制硫酸銨：</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">氨在廢水中主要以銨離子（</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">NH<sub>4</sub><sup>+</sup></span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">）和游離氨（</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">NH<sub>3</sub></span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">）狀態(tài)存在，其轉變關(guān)系為：</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">NH<sub>3</sub>+H<sub>2</sub>O—NH<sub>4</sub><sup>+</sup>+OH<sup>-</sup></span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">，這個(gè)關(guān)系受</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">pH</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">值影響，當</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">pH</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">值高時(shí)，氨氮轉變成游離氨，游離氨的比例增大。常溫時(shí)，當</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">pH</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">值為</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">7</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">左右時(shí)氨氮大多數以銨離子狀態(tài)存在，而</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">pH</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">為</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">11</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">左右時(shí)，游離氨大致占</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">98%</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">。一般通過(guò)</span><span style="font-size: 19px; font-family: "Times New Roman", serif; background: white;">pH</span><span style="font-family: 宋體, SimSun; font-size: 19px; background: white;">調節，促進(jìn)氨轉化為游離氨，利用吹脫塔將廢水中的氨轉化為含氨氣體通過(guò)吹脫塔頂部采出，含氨氣體</span><span style="font-family: 宋體, SimSun; font-size: 19px; color: black;">經(jīng)過(guò)反應器直接與硫酸反應制取硫酸銨產(chǎn)品。</span></span></p><p style="line-height: 2em;"><span style="font-size: 20px; font-family: 宋體, SimSun;"><strong><span style="font-family: 宋體, SimSun; font-size: 19px; color: rgb(102, 102, 102);">2</span></strong><strong><span style="font-size: 19px; font-family: 宋體; color: rgb(102, 102, 102);">、應用領(lǐng)域</span></strong></span></p><p style="margin: 5px 0px; text-indent: 32px; line-height: 2em;"><span style="color: black; font-size: 20px; font-family: 宋體, SimSun;">各類(lèi)石油煉制、煤氣化、焦化、化工、制藥等企業(yè)產(chǎn)生的不同濃度的含氨廢水。</span></p><p style="line-height: 2em;"><span style="font-size: 20px; font-family: 宋體, SimSun;"><strong><span style="font-family: 宋體, SimSun; font-size: 19px; color: rgb(102, 102, 102);">3</span></strong><strong><span style="font-size: 19px; font-family: 宋體; color: rgb(102, 102, 102);">、硫酸銨產(chǎn)品的用途</span></strong></span></p><p style="text-indent: 37px; line-height: 2em;"><span style="font-size: 20px; font-family: 宋體, SimSun;"><span style="font-family: 宋體, SimSun; font-size: 19px; color: rgb(102, 102, 102);">硫酸銨，簡(jiǎn)稱(chēng)硫銨（化學(xué)式</span><span style="font-size: 19px; font-family: "Times New Roman", serif; color: rgb(102, 102, 102);">(NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub></span><span style="font-family: 宋體, SimSun; font-size: 19px; color: rgb(102, 102, 102);">），一般為白色顆粒。無(wú)氣味，</span><span style="font-size: 19px; font-family: "Times New Roman", serif; color: rgb(102, 102, 102);">280℃</span><span style="font-family: 宋體, SimSun; font-size: 19px; color: rgb(102, 102, 102);">以上分解，易溶于水，不溶于乙醇和丙酮。硫銨主要用作農用肥料，適用于各種土壤和作物，也用于各種復合肥的混摻原料。還可用于紡織、皮革、采礦等方面。</span></span></p><p style="text-indent: 37px; line-height: 2em;"><span style="color: rgb(102, 102, 102); font-size: 20px; font-family: 宋體, SimSun;"><br/></span></p><p style="text-indent: 37px; line-height: 2em;"><span style="color: rgb(102, 102, 102); font-size: 20px; font-family: 宋體, SimSun;"><img 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